Do mixing models with different input requirement yield similar streamflow source contributions? Case study: A tropical montane catchment     

Jorge Ramón  Alicia Correa  Edison Timbe  Giovanny M. Mosquera  Enma Mora  Patricio Crespo 《水文研究》2021,35(6):e14209

Hydrogeochemical based mixing models have been successfully used to investigate the composition and source identification of streamflow. The applicability of these models is limited due to the high costs associated with data collection and the hydrogeochemical analysis of water samples. Fortunately, a variety of mixing models exist, requiting different amount of data as input, and in data scarce regions it is likely that preference will be given to models with the lowest requirement of input data. An unanswered question is if models with high or low input requirement are equally accurate. To this end, the performance of two mixing models with different input requirement, the mixing model analysis (MMA) and the end-member mixing analysis (EMMA), were verified on a tropical montane headwater catchment (21.7 km²) in the Ecuadorian Andes. Nineteen hydrogeochemical tracers were measured on water samples collected weekly during 3 years in streamflow and eight potential water sources or end-members (precipitation, lake water, soil water from different horizons and springs). Results based on 6 conservative tracers, revealed that EMMA (using all tracers) and MMA (using pair-combinations out of the 6 conservative ones), identified the same end-members: rainfall, soil water and spring water., as well as, similar contribution fractions to streamflow from rainfall 21.9% and 21.4%, soil water 52.7% and 52.3%, and spring water 26.1% and 28.7%, respectively. Our findings show that a hydrogeochemical mixing model requiring a few tracers can provide similar outcomes than models demanding more tracers as input data. This underlines the value of a preliminary detailed hydrogeochemical characterization as basis to derive the most cost-efficient monitoring strategy.  相似文献   

深渊着陆器坐底位置的精确测量和反演计算          下载免费PDF全文

陈瀚  丘学林  贺恩远  王元  陈传绪  陈俊 《地球物理学报》2019,62(5):1744-1754

深渊着陆器在下潜过程中,由于受到海流的影响,其坐底位置会偏离投放点,偏离量和偏离方向很难估计,而声学水下定位方法在深渊海区不太适用.通过在海面进行气枪十字放炮作业,利用炮点准确位置和时间信息,以及海底地震仪(Ocean Bottom Seismometer,OBS)记录的直达水波到时,对深渊着陆器的坐底位置进行精确测量可以提供有效定位数据.该方法对采集得到的数据进行预处理,使用蒙托卡洛方法结合最小二乘法,对万泉号着陆器实际坐底位置进行了反演校正,得到三个潜次的位置校正偏移量分别为211m、178m、861m,偏移方向各不相同,校正精度为±20m,比以往的定位精度大为提高.此外,该方法测量确定了三个海底标志物的精确位置,为未来万米无人或载人潜器提供了可靠的水下参考坐标.  相似文献   

Volatile element chemistry during accretion of the earth     

《Chemie der Erde / Geochemistry》2020,80(1):125594

We review some issues relevant to volatile element chemistry during accretion of the Earth with an emphasis on historical development of ideas during the past century and on issues we think are important. These ideas and issues include the following: (1) whether or not the Earth accreted hot and the geochemical evidence for high temperatures during its formation, (2) some chemical consequences of the Earth’s formation before dissipation of solar nebular gas, (3) the building blocks of the Earth, (4) the composition of the Earth and its lithophile volatility trend, (5) chemistry of silicate vapor and steam atmospheres during Earth’s formation, (6) vapor - melt partitioning and possible loss of volatile elements, (7) insights from hot rocky extrasolar planets. We include tabulated chemical kinetic data for high-temperature elementary reactions in silicate vapor and steam atmospheres. We finish with a summary of the known and unknown issues along with suggestions for future work.  相似文献   

青藏高原凯蒙蛇绿混杂岩中碱性火山岩的发现及意义     

潘政  史仁灯  黄启帅  陈生生  龚小晗  吴钪  杨可 《岩石矿物学杂志》2020,39(1):18-34

班公湖-怒江洋的关闭时间直接制约青藏高原早期构造演化的认识。最近,在班公湖-怒江缝合带南侧凯蒙蛇绿混杂岩中发现一碱性火山岩,岩性主要是橄榄粗安岩,具粗面结构,斑晶主要是更长石和少量普通辉石,基质主要由更长石、普通辉石和少量填隙的碱性长石组成,有的具辉绿结构。岩石化学成分较一致,Si O2含量介于51.34%~53.91%之间,Ti O2含量为1.02%~1.55%,具有高Al2O3(17.06%~18.46%)和Na2O(4.90%~6.36%)、低K2O(0.05%~0.88%)含量特点,大多数Mg#大于60,最高68.62,里特曼指数(σ)介于3.65~4.47之间,为碱性系列火山岩;富集Sr、Rb、Ba等大离子亲石元素,亏损Nb、Y、Yb等高场强元素,相对富集Zr、Ti,Nb/U、Zr/Nb、La/Yb等比值稳定,分别为7.45~8.51、15.92~17.26和7.26~8.06;(87Sr/86Sr)i值变化范围较小,介于0.706~0.707之间,(143Nd/144Nd)t值在0.512 368~0.512 548之间,说明源区较为一致,结合Ce/Pb-Si O2图解判断结果,认为凯蒙碱性火山岩具有原始地幔、陆壳和深海沉积物源区混合特征。锆石U-Pb同位素定年结果表明该火山岩年龄为101.8±1.1 Ma,可能形成于洋壳俯冲阶段末期,由大陆边缘陆壳与俯冲洋壳板片断离导致软流圈地幔上涌诱发部分熔融所致,推测班公湖-怒江洋大约在早白垩世晚期关闭。  相似文献   

西太平洋Y3海山对营养盐的影响及其生态环境效应     

马骏  宋金明  李学刚  袁华茂  李宁  段丽琴  王启栋 《地学前缘》2020,27(4):322-331

作为大洋典型地貌特征的海山,其邻近的海洋生境并不被人熟知。依据2014年冬季对热带西太平洋Y3海山及其邻近海域的综合调查,首次探讨了该海山区海水中营养盐的分布特征及其与生态环境的耦合关系。结果表明Y3海山区是典型的热带寡营养海域。在50~125 m的深度,温跃层和高盐区双重作用对底部高浓度营养盐向上输送的阻碍,是导致真光层上部营养盐浓度较低的重要原因;同时,浮游植物和异养细菌的消耗也加剧了该区域营养盐的缺乏。Y3海山突出的地形地貌对营养盐的分布产生重要的影响,海山对流经的海流产生阻碍,形成上升流,使底部高浓度的营养盐突破温跃层和高盐区的阻碍向上输送,从而使海山周围营养盐的平均浓度高于远离海山的海域。相关性分析显示,Y3海山区真光层中营养盐浓度与温度、盐度、叶绿素a浓度和异养细菌丰度分别呈负相关、正相关、负相关(除NO₂-N外)和负相关关系。海山区特殊的营养盐分布及其与生态环境的耦合是其成为一种独特的大洋生态系统的重要因素。  相似文献   

小兴安岭-张广才岭铁力地区侏罗纪辉绿岩年代学、地球化学、锆石Hf同位素特征及其构造意义   总被引：1，自引：0，他引：1  

葛茂卉  张进江  刘恺 《岩石学报》2020,36(3):726-740

小兴安岭-张广才岭地区中生代岩浆活动的成因及动力学背景对于揭示古太平洋的构造演化具有重要意义。本文选取小兴安岭-张广才岭铁力地区出露的辉绿岩墙为研究对象,进行锆石LA-ICP-MS U-Pb年代学、全岩地球化学和锆石Hf同位素等分析,对该基性岩的形成时代、岩石成因、岩浆源区以及形成的大地构造背景进行讨论。研究表明:辉绿岩锆石具有高Th/U比值( 0.3),CL图像显示微弱的振荡环带结构,具有岩浆锆石特征,~(206)Pb/~(238)U加权平均年龄为187±2Ma,即形成于早侏罗世;该岩体主要经历了橄榄石和单斜辉石的分离结晶作用,未遭受明显的地壳混染作用,并且具有Rb、Ba、U、Pb、K和Sr等流体活动元素相对富集,Th、Nb和Ta等非流体活动性元素相对亏损的地球化学特征,暗示其形成于被俯冲流体富集交代的亏损地幔部分熔融,源区可能为尖晶石-石榴石二辉橄榄岩,部分熔融程度约为6%～20%。结合该地区同时代的岩浆岩、变形构造、矿床特征和黑龙江蓝片岩的相关报道,本文认为小兴安岭-张广才岭地区在中生代期间处于活动大陆边缘环境,其岩浆岩的形成主要是由于存在于佳木斯地块和松嫩-小兴安岭地块间的牡丹江洋西向俯冲造成的。  相似文献   

超慢速扩张环境下超镁铁质岩系统的热液硫化物成矿机理以及启示     

曹红  孙治雷  刘昌岭  姜学钧  何拥军  黄威  尚鲁宁  王利波  张喜林  耿威  施美娟  李东义 《海洋学报》2018,40(4):61-75

西南印度洋63.5°E热液区是在超慢速扩张洋脊发现的首个超镁铁质岩热液系统。对取自该区的热液硫化物样品进行了系统的矿物学和地球化学分析，矿物学分析结果表明:该热液区硫化物为富Fe型高温硫化物，且经历了较深程度的氧化蚀变，大量中间态的Fe氧化物充填在硫化物矿物间的孔隙及内部解理中；这些硫化物相以白铁矿为主，其次是等轴古巴矿和少量铜蓝，缺乏黄铁矿、闪锌矿。据推断，该区的热液成矿作用分为4个阶段:低温白铁矿阶段→高温等轴古巴矿阶段→自形白铁矿阶段→后期海底风化阶段（少量铜蓝以及大量的Fe的羟氧化物）。与之相对应，地球化学分析结果表明这些硫化物的Fe含量较高（31.57%~44.59%），Cu含量次之（0.16%~7.24%），而Zn含量普遍较低（0.01%~0.11%）；微量元素较为富集Co（328×10-6~2 400×10-6）和Mn（48.5×10-6~1 730×10-6）。该区硫化物中较高含量的Fe、Co与超镁铁质岩热液系统相似，明显高于镁铁质岩热液系统。独特的热液硫化物矿物学特征和元素组成可能与该区普遍出露的地幔岩、橄榄岩蛇纹石化作用以及拆离断层的广泛发育的环境有关。  相似文献   

Continuous real‐time analysis of the isotopic composition of precipitation during tropical rain events: Insights into tropical convection          下载免费PDF全文

Shaoneng He  Nathalie F. Goodkin  Dominik Jackisch  Maria Rosabelle Ong  Dhrubajyoti Samanta 《水文研究》2018,32(11):1531-1545

To investigate stable isotopic variability of precipitation in Singapore, we continuously analysed the δ‐value of individual rain events from November 2014 to August 2017 using an online system composed of a diffusion sampler coupled to Cavity Ring‐Down Spectrometer. Over this period, the average value (δ¹⁸O_Avg), the lowest value (δ¹⁸O_Low), and the initial value (δ¹⁸O_Init) varied significantly, ranging from ?0.45 to ?15.54‰, ?0.9 to ?17.65‰, and 0 to ?13.13‰, respectively. All 3 values share similar variability, and events with low δ¹⁸O_Low and δ¹⁸O_Avg values have low δ¹⁸O_Init value. Individual events have limited intraevent variability in δ‐value (Δδ) with the majority having a Δδ below 4‰. Correlation of δ¹⁸O_Low and δ¹⁸O_Avg with δ¹⁸O_Init is much higher than that with Δδ, suggesting that convective activities prior to events have more control over δ‐value than on‐site convective activities. The d‐excess of events also varies considerably in response to the seasonal variation in moisture sources. A 2‐month running mean analysis of δ¹⁸O reveals clear seasonal and interannual variability. Seasonal variability is associated with the meridional movement of the Intertropical Convergence Zone and evolution of the Asian monsoon. El Niño–Southern Oscillation is a likely driver of interannual variability. During 2015–2016, the strongest El Niño year in recorded history, the majority of events have a δ¹⁸O value higher than the weighted average δ¹⁸O of daily precipitation. δ¹⁸O shows a positive correlation with outgoing longwave radiation in the western Pacific and the Asian monsoon region, and also with Oceanic Niño Index. During El Niño, the convection centre shifts eastward to the central/eastern Pacific, weakening convective activities in Southeast Asia. Our study shows that precipitation δ‐value contains information about El Niño–Southern Oscillation and the Intertropical Convergence Zone, which has a significant implication for the interpretation of water isotope data and understanding of hydrological processes in tropical regions.  相似文献   

热带西太平洋砂壳纤毛虫的多样性     

李海波  张武昌  赵苑  赵丽  董逸  王超锋  梁晨  肖天 《海洋学报(英文版)》2018,37(10):218-228

为了探明热带西太平洋海区砂壳纤毛虫的多样性、垂直分布及纬向变化，我们于2012年11-12月在该海区四个断面采集了0-200 m的水样。共检出砂壳纤毛虫39属124种，多数种类喜好生活在表层和次表层。砂壳纤毛虫种丰富度、丰度以及多样性指数的高值主要出现在比叶绿素浓度最大值稍浅的位置，与温度和叶绿素浓度显著正相关，与盐度和采样深度显著负相关。多数优势种与环境因子间的相关性不显著。热带西太平洋海区砂壳纤毛虫多样性极高，各站种丰富度在25-52之间。在从表层至75 m处的多数采样点香农指数均大于3。该海区砂壳纤毛虫冗余种的比例很高，占砂壳纤毛虫总种类数的87.90%，贡献了砂壳纤毛虫60.38%的丰度，表明热带西太平洋海区砂壳纤毛虫群落对饵料组成和摄食压力改变的应对能力很强，稳定性很高。  相似文献   

Water transport and tracer mixing in volcanic ash soils at a tropical hillslope: A wet layered sloping sponge     

Giovanny M. Mosquera  Patricio Crespo  Lutz Breuer  Jan Feyen  David Windhorst 《水文研究》2020,34(9):2032-2047

Andosol soils formed in volcanic ash provide key hydrological services in montane environments. To unravel the subsurface water transport and tracer mixing in these soils we conducted a detailed characterization of soil properties and analyzed a 3-year data set of sub-hourly hydrometric and weekly stable isotope data collected at three locations along a steep hillslope. A weakly developed (52–61 cm depth), highly organic andic (Ah) horizon overlaying a mineral (C) horizon was identified, both showing relatively similar properties and subsurface flow dynamics along the hillslope. Soil moisture observations in the Ah horizon showed a fast responding (few hours) “rooted” layer to a depth of 15 cm, overlying a “perched” layer that remained near saturated year-round. The formation of the latter results from the high organic matter (33–42%) and clay (29–31%) content of the Ah horizon and an abrupt hydraulic conductivity reduction in this layer with respect to the rooted layer above. Isotopic signatures revealed that water resides within this soil horizon for short periods, both at the rooted (2 weeks) and perched (4 weeks) layer. A fast soil moisture reaction during rainfall events was also observed in the C horizon, with response times similar to those in the rooted layer. These results indicate that despite the perched layer, which helps sustain the water storage of the soil, a fast vertical mobilization of water through the entire soil profile occurs during rainfall events. The latter being the result of the fast transmissivity of hydraulic potentials through the porous matrix of the Andosols, as evidenced by the exponential shape of the water retention curves of the subsequent horizons. These findings demonstrate that the hydrological behavior of volcanic ash soils resembles that of a “layered sponge,” in which vertical flow paths dominate.  相似文献